Geochemistry and environment evolution of Core E in the Laizhou Bay since last stage of Middle Pleistocene     

Han Deliang  Yu Hongjun  Li Guanbao 《海洋学报(英文版)》2001,20(3):391-399

IwrincrIONOn the evolution of palcoenvironment, salt-water encroachmnt and the distributionof subsurface brine in the LaizhOu Bay area, many researches had been carried out, and muchknowledge abeut the gcolOgical features in this area since Late QUaternary was aCquired' ) (H8nand Wu, l992; Han and Meng, l994; Wen et al. l989). However there was IittIe studyon the sediment geOChemical characteristics since Quaternary. In this Paper, the element strati-graphic characteristics and evolut…  相似文献   

Geochemical and hydrodynamic constraints on the distribution of trace metal concentrations in the lagoon of Nouméa, New Caledonia   总被引：1，自引：0，他引：1  

Christophe Migon  Sylvain Ouillon  Xavier Mari  Emmanuel Nicolas 《Estuarine, Coastal and Shelf Science》2007,74(4):756

Seawater samples were collected in the lagoon of Nouméa (southwest New Caledonia) along two transects from eutrophic coastal bays to the oligotrophic barrier reef. Land-based emissions to the lagoon were measured with dissolved and particulate concentrations of chromium (Cr) and nickel (Ni), used as tracers of both terrigenous and industrial (Ni ore treatment) activities, as well as dissolved and particulate concentrations of zinc (Zn), used as a tracer of urban effluents. The spatial variability of metal concentrations was related to geochemical and hydrodynamic conditions, i.e., respectively: (1) natural and anthropogenic emission sources, and chemical processes occurring in the water column; and (2) water residence times. The parameter used to describe the residence time of water masses was the local e-flushing time, i.e. the time required for a tracer mass contained within a given station to be reduced by a factor 1/e. High metal concentrations were found in coastal areas (up to 9000 ng dissolved Ni L⁻¹), and steeply decreased with distance from the coast (down to 101 ng dissolved Ni L⁻¹ near the barrier reef) to reach levels similar to those found in remote Pacific waters, suggesting a rapid renewal of waters close to the barrier. Distributions of metals in the lagoon are controlled upstream by land-based emission sources and later chemical processes. Then hydrodynamics constrain metal distributions, as shown by the observed relationship between local e-flushing times and the spatial variability of metal concentrations. In addition, a change in the direction of prevailing winds yielded a decrease of dissolved metal concentrations at the same site by a factor of 2.5 (Cr and Ni) and 2.9 (Zn). It is suggested that the residence time is a key parameter in the control of elemental concentrations in the lagoon waters, as much as land-based emission sources.  相似文献   

细菌、病毒与浮游植物相互关系及其对海洋地球化学循环的作用   总被引：9，自引：0，他引：9  

周玉航  潘建明  叶瑛  周怀阳 《台湾海峡》2001,20(3):340-345

本文综述了近年来国内外在海洋地球化学循环，特别是微生物环研究方面的发展现状，探讨了浮游植物，细菌，病毒相互之间的关系及其对海洋地球化学循环的影响。  相似文献   

西菲律宾海沉积物铁族元素地球化学   总被引：5，自引：1，他引：5  

石学法  陈丽蓉 《海洋地质与第四纪地质》1993,13(1):73-84

本文对取自西菲律宾海区的三个柱状沉积物岩芯的铁族元素地球化学行为进行了系统的研究。从元素的含量及剖面变化、元素的相关性及组合特征,铁族元素与主元素的关系以及元素的赋存状态等方面探讨了物质来源、沉积作用和古气候,并据此进行了地层划分。沉积物有4种来源:海底火山源、生物源、自生源和陆源。海底火山物质提供了较多的铁族元素,相形之下,自生沉积作用较弱。元素地层学研究表明,在全新世温暖期和晚更新世寒冷期铁族元素表现出不同的地球化学行为,尤以Mn和亲生物(Ca)元素对气候的反映灵敏。WP_2孔和WP_(40)孔铁族元素特征相似,与WP_1孔差别较大。  相似文献   

Retention of arsenic and phosphorus in iron-rich concretions of Tagus salt marshes   总被引：1，自引：0，他引：1  

Miguel Caetano  Carlos Vale 《Marine Chemistry》2002,79(3-4)

Iron-rich concretions are frequently found around plant roots in Tagus estuary (Portugal) where radial delivery of O₂ takes place. Salt marsh sediments exhibit cracks that are an additional feature to introduce O₂ and other solutes in the upper sediments. Metal concentrations in salt marsh sediments are clearly above the background levels reflecting the anthropogenic sources from a large city with 2.5 million inhabitants, and several industrial centres. In order to evaluate how both oxidised structures influences the redistribution of redox sensitive elements in salt marsh sediments, concretions were collected from roots of Halimione portucaloides below the oxygenated zone. These tubular cylindrical structures were analysed for Fe, Al, Mn, As, and P along 1-cm radial transect in a millimetre scale from the inner part to the adjacent anoxic sediment. In addition, oxidised cracks were analysed for the same spatial resolution, from the sediment–water interface to anoxic layers (2-cm transept). The parallelism between Fe, As, and P concentrations at this microscale is the most noticeable aspect. Iron and As presented very high concentrations in the 4-mm concretions (3.4 mmol g⁻¹ and 3.1 μmol g⁻¹, respectively) and decreased sharply to the host sediment. Oxygen released from roots oxidise the solid sulphides, and the reduced Fe and As are transported towards the root by both diffusion and pore water flow associated with the root water uptake. Subsequently, Fe(III) precipitates and As is retained by sorption and/or coprecipitation. These elements are also enriched in the first 2-mm of oxidised cracks, but in lower concentrations (50% and 30%, respectively). Manganese concentrations in concretions were low (11.8 μmol g⁻¹), indicating that Fe dominates the sediment chemistry. Phosphorus and iron concentrations in the ascorbate fraction were higher in the oxidising surfaces of concretions (10.7 μmol g⁻¹ and 1.6 mmol g⁻¹, respectively) and of cracks (5.1 μmol g⁻¹ and 0.47 mmol g⁻¹). The parallelism of Fe and As distributions includes not only their similar redox chemistries, but also that to phosphate, including control by coprecipitation of the host iron phases. The mechanisms involved in the mobilisation of As and P are however different, whereas As comes from the oxidation of iron sulphides; dissolved P derives from reduction of ferri-hydroxide phases.  相似文献   

Advances in the Study of Geochemistry and Paleo-oceanography of the Co-rich Crust     

Cai Yihua  HUANG Yipu 《海洋通报(英文版)》2002,4(2)

The current advances in the study of geochemistry and paleo-oceanography of the Co-rich crust are reviewed in this paper. We summarize the study of geochemistry of the Co-rich crust, discuss the diffusion of elements in the Co-rich crust and the exchange with ambient seawater. Besides, we discuss the effect of phosphatization and substrate rocks on the composition of the Co-rich crust. We also introduce the application of stable isotopes (including the stable isotopes of Pb, Nd, and Hf), radioactive isotopes (including the radioactive isotopes of Be, U and Th), and elements (including the major elements, minor elements and rare earth elements) to the study of paleo-oceanography of the Co-rich crust.  相似文献   

东太平洋沉积物U的地球化学   总被引：4，自引：0，他引：4  

刘季花  梁宏锋 《海洋地质与第四纪地质》1996,16(1):59-67

本文对地矿部“海洋四号”科学考察船１９８７－１９８９年在东赤道太平洋ＣＣ区所取得的２７个深海表层沉积样品进行Ｕ的地球化学分析，探讨了Ｕ在深海沉积中的地球化学行为，结果表明，不同类型沉积的Ｕ含量不同，平均值由大至小的次序的含沸石粘土（２．１６×１０＾－６），硅质粘土（１．９５×１０＾－６），硅质软泥（１．６５×１０＾－６），钙质硅质粘土（１．５９×１０＾－６），在同类型沉积中Ｕ的分散性较大；Ｕ在区域  相似文献   

南海西沙西南海域表层沉积物特征   总被引：3，自引：1，他引：3  

邱燕  姚伯初 《海洋地质与第四纪地质》1997,17(4):41-53

西沙西南海域表层沉积物样品矿物成分，地球化学，微体古生物分析测试结果表明：沉积物可分为７种类型，沉积环境主要是陆坡，部分为深海平原，海洋生物，海洋化学以及火山物质的沉积起到了积极的作用，陆源物质的影响较小，它们主要来源于北部大陆和南部岛礁等物源区。  相似文献   

氧同位素分析在东濮凹陷下第三纪沉积环境中的应用   总被引：2，自引：0，他引：2  

史忠生  陈开远  史军  柳保军  何胡军  刘刚 《海洋地质前沿》2003,19(5):29-33

主要介绍了氧同位素的地球化学特征，并利用这些特征在沉积环境方面的指示意义，分析了东濮凹陷下第三系盐湖沉积的氧同位素。分析结果表明：尽管保存在碳酸盐中的氧同位素的值不能定量地反映原始氧同位素的值，不能够作为区分海陆相的标志，但它可以定性地探讨碳酸盐沉积时的沉积环境。通过对东濮凹陷下第三系盐湖沉积的氧同位素分析发现，从沙四上到沙一时期，除了沙三上的δ^18O有些突变外，基本上呈递增趋势。这反映出，从沙四上到沙一时期该区的气候逐渐向干早过渡；沙四上到沙三上一段δ＾18Ｏ明显比沙一和沙二上伯低，说明在沙四上到沙三上时期，该沉积区的蒸发作用还不是很显著，而另一方面也说明在由沙三上向沙二上过渡时，该区可能存在一次气候突变，使得沙二上和沙一时期的蒸发量远大于降雨量，δ^18O的值也因此迅速增大。同时，也做了碳酸盐同位素系数Z值的研究，其揭示的沉积环境特征与氧同位素基本相同。  相似文献   

长江口南支沉积物元素地球化学分区与环境指示意义   总被引：5，自引：0，他引：5  

王国庆  石学法  刘焱光  窦衍光 《海洋科学进展》2007,25(4):408-418

对采自长江口南支的130个表层底质沉积物样品采用X射线荧光光谱法进行了20种常、微量元素的地球化学分析。在此基础上,应用系统聚类法对该区域进行了元素地球化学分区。研究结果表明,研究区主要可以分为两大地球化学分区:Ⅰ区以相对富集SiO2,Sr,Zr元素为典型特征,主要涵盖5 m等深线以浅的长江三角洲前缘区;Ⅱ区以相对富集Al2O3,TFe2O3(全铁),MgO,Pb元素为典型特征,涵盖了前三角洲的广大区域。从地球化学分区的空间分布来分析,这两个分区元素之间的差异反映的是沉积水动力条件与沉积介质物化性质这两个环境要素空间分布的差异性,即在研究区内,表层沉积物元素地球化学空间分布的差异性实质上反映了沉积环境空间分布的差异性。  相似文献